If those photos were available contemporaneously, like in a book, magazine, or newspaper dated 1868, you might be able to legally use them.
But if they were handed down by the family or estate and then provided to the recent book or website it's possible that you could not.
Those are just guesses on my part.
You would be wise to engage an intellectual property attorney to guide you through this.
Otherwise you might find yourself losing every nickel you make on your book and then some.